强火源条件下瓦斯点火化学热力学特征
Chemical Thermodynamics Characteristics of Gas Ignition Under Strong Fire Source
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摘要: 从基元反应、化学热力学2个方面分析了强火源条件下瓦斯点火的压力峰值、火焰传播速度的变化特征。结果表明,强火源加速了基元反应进程,使自由基产生速度加快,导致瓦斯气体迅速进入自热阶段,同时提高了爆炸压力峰值和压力上升速度,加剧了爆炸强度。Abstract: The change characteristics of pressure peak and flame propagation speed under strong fire source were analyzed from two aspects of elementary reaction and chemical thermodynamics. Analysis result show that the strong fire source can accelerate elementary reaction process, and make radicals produced faster, which leads the gas quickly into self-heating stage, and improves the explosion pressure peak and pressure rise rate to contribute to the explosion intensity.