煤体表面粗糙度对非阳离子表面活性剂润湿性影响的实验研究

    Experimental study on the influence of coal surface roughness on wettability of non-cationic surfactants

    • 摘要: 在水中加入非阳离子表面活性剂可有效增强水对煤体表面的润湿性,煤体表面的润湿性受溶液种类和煤体表面物理化学性质影响。为研究煤体粗糙度对表面润湿性的影响,采用5种不同表面粗糙度的型煤和5种非阳离子表面活性剂,使用SJ-210表面粗糙度测量仪、JC2000D型动态接触角测量仪等设备进行实验,分别计算了各溶液润湿型煤的表面能。结果表明:型煤表面粗糙度介于0.5~5 μm之间,非阳离子表面活性剂溶液在型煤表面形成的接触角与型煤表面粗糙度呈负相关,型煤表面能与表面粗糙度呈正相关;非阳离子表面活性剂质量分数0.01%时,型煤表面粗糙度对脂肪醇聚氧乙烯醚润湿性的影响程度最大,质量分数0.05%时,对癸基葡萄糖苷影响最大,质量分数0.10%时,对十二烷基硫酸钠影响最大,质量分数0.20%时,对脂肪醇聚氧乙烯醚羧酸钠影响最大,质量分数0.40%时,对癸基葡萄糖苷影响最大;质量分数越低的表面活性剂润湿性受型煤表面粗糙度影响越大,在实验室使用低质量分数表面活性剂溶液对型煤进行润湿实验时,控制型煤的表面粗糙度具有重要意义。

       

      Abstract: Adding non-cationic surfactant in water can effectively enhance the wettability of water on coal surface, and the wettability of coal surface is affected by the type of solution and the physical and chemical properties of coal surface. In order to study the influence of the roughness of the surface wettability of coal, five types of coal with different surface roughness and 5 non-cationic surfactants, SJ-210 surface roughness measuring instrument, JC2000D dynamic contact angle measuring instrument and other equipment were used for experiments, the surface energy of briquette wetted by each solution was calculated. The results show that the briquette surface roughness is in the range of 0.5 μm to 5 μm. The contact angle formed by non-cationic surfactant solution on briquette surface is negatively correlated with the briquette surface roughness, and the briquette surface energy is positively correlated with the briquette surface roughness; when the mass fraction of non-cationic surfactant is 0.01%, the surfaceroughness of briquette has the greatest influence on the wettability of fatty alcohol polyoxyethylene ether; when the mass fraction is 0.05%, it has the greatest influence on decyl glucoside; when the mass fraction is 0.10%, it has the greatest influence on sodium dodecyl sulfate; when the mass fraction is 0.20%, the surface roughness of briquette has the greatest influence on the wettability of fatty alcohol polyoxyethylene ether. When the mass fraction was 0.40%, it had the greatest influence on decyl glucoside; the wettability of surfactant with lower mass fraction is more affected by briquette surface roughness. It is of great significance to control briquette surface roughness by using low-concentration surfactant solution to conduct briquette wettability experiment in laboratory.

       

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