基于绝热氧化实验的不同惰性气体阻燃效果研究

    Research on flame retardant effects of different inert gases based on adiabatic oxidation experiment

    • 摘要: 为掌握在煤炭不同氧化阶段不同惰气阻燃的差异性,采用绝热氧化装置,以非吸附性He为参考气体,设计不同温度起点(70、110、150℃)的注惰气(N2、CO2)阻燃实验。以惰气注入后煤样温度、O2体积分数为考核指标,对比研究了不同惰气的阻燃效果。结果表明:实验煤样的表观活化能为47 kJ/mol,自燃临界温度为83 ℃;初始温度越高,降温至30 ℃所需的时间越长;在同一初始温度下注入不同惰气后,He的阻燃效果最佳,N2次之,CO2最差,N2和CO2对O2的置换速率随着温度升高而增大;温度起点相同时,注入N2的降温速率和相对置换量均比注入CO2的大,N2的阻燃效率比CO2的好。

       

      Abstract: To grasp the difference of different inert gas flame retardancy in different oxidation stages of coal, in this paper, an adiabatic oxidation device is used, and non-adsorbable helium is used as the reference gas to design inert (N2、CO2) flame retardant experiments with different initial temperatures (70、110、150℃). Taking the temperature and oxygen concentration of the coal sample after inert gas injection as assessment indicators, the flame-retardant effects of different inert gases were compared and studied. The results show that the apparent activation energy of the experimental coal sample is 47 kJ/mol, and the critical temperature of spontaneous combustion is 83 ℃. The higher the initial temperature, the longer it takes to cool down to 30 ℃. After injecting different inert gases at the same initial temperature, helium has the best flame retardant effect, followed by nitrogen, and carbon dioxide is the worst. The replacement rate of nitrogen and carbon dioxide for oxygen increases with the increase of temperature. When the initial temperature is the same, the cooling rate and relative displacement of nitrogen injected are larger than those of carbon dioxide injected, and the flame retardant efficiency of nitrogen is better than that of carbon dioxide.

       

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