氧化剂处理前后煤孔隙分形特征研究

    Study on fractal characteristics of coal pore before and after oxidation treatment

    • 摘要: 为了探究氧化剂对煤孔隙分形特征的影响,采集了千秋矿低阶煤、沙曲矿中阶煤和中马村矿的高阶煤样,使用二氧化氯和过硫酸铵对不同煤阶的煤样进行预处理,利用压汞法对氧化剂处理前后煤样的孔隙结构进行分析,并计算了其孔隙分形维数,同时分析了分形维数与曲折度和孔隙度的关系。结果表明:随煤阶升高,孔隙分形维数逐渐降低;经氧化剂处理后,煤样孔隙分形维数、曲折度和孔隙度均有不同程度的增大,表明氧化剂能够提高煤孔隙的复杂性同时有利于煤层气的解吸运移,且二氧化氯比过硫酸铵的促进效果更加明显;随孔隙分形维数增大,曲折度先减小后增大,孔隙分形维数D=2.80约为趋势线转折点,孔隙度则呈下降趋势。

       

      Abstract: In order to explore the influence of oxidants on the fractal characteristics of coal pores, samples of low-rank coal from Qianqiu Mine, medium-rank coal from Shaqu Mine and high-rank coal from Zhongma Mine were collected, and coal samples of different coal ranks were pretreated with chlorine dioxide and ammonium persulfate. The pore structure of coal samples before and after oxidant treatment was analyzed, and the pore fractal dimension was calculated. At the same time, the relationship between fractal dimension and tortuosity and porosity was analyzed. The results show that as the coal rank increases, the pore fractal dimension gradually decreases; after treatment with oxidant, the coal sample pore fractal dimension, tortuosity and porosity all increase in different degrees, indicating that the oxidant can increase the complexity of coal pores. At the same time, it is conducive to the desorption and transport of coalbed methane, and the promotion effect of chlorine dioxide is more obvious than that of ammonium persulfate; as the pore fractal dimension increases, the tortuosity decreases first and then increases. The pore fractal dimension D=2.80 is approximate the turning point of the trend line, and the porosity shows a downward trend.

       

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