Abstract: The emergency capability management of coal enterprises is the most important content of coal mine safety management. Constructing assessment model of emergency capability and applying it effectively is significant for coal enterprises to decrease coal production accidents and reduce the loss of production accidents. In order to improve the emergency capabilities in coal enterprise, the paper summarizes the assessment index system of emergency capability of safe production in coal enterprise based on the existing literature, consisting of four first class indices and twenty-two secondary indices. Moreover, the paper builds a new assessment model of emergency capability in coal enterprises based on ANP and triangular fuzzy number. Finally, the paper takes an example of a coal enterprise and uses the model to assess the emergency capability, and the effectiveness of the model is verified by the application.