壳聚糖基吸水树脂抑尘微胶囊制备及特性研究

    Preparation and properties of chitosan-based water-absorbent resin dust-suppressing microcapsules

    • 摘要: 为了减轻煤矿行业粉尘灾害,降低煤矿工人患尘肺病概率,采用接枝共聚的方法,以聚乙烯醇为抑尘剂基体材料,在引发剂与交联剂作用下,将2-丙烯酰胺-2-甲基丙磺酸及丙烯酸与基体接枝共聚,制备出高吸水树脂作为微胶囊芯材,以壳聚糖为壁材,通过壳聚糖与戊二醛的胺醛缩合作用制备出新型吸水树脂抑尘微胶囊;通过红外光谱分析、扫描电镜确定吸水树脂及其微胶囊包覆情况,研究吸水树脂及其微胶囊的溶胀性、保湿性、抗风蚀性、生物降解性等。结果表明:微胶囊可溶胀23倍,经12 h后质量损失仅有19.6 %;在抗风蚀性能实验中,在13 m/s的风速下,微胶囊抑尘剂的抑尘效率高达91.98 %,抑制了煤尘扩散;且在自然环境下22 d后,微胶囊抑尘剂可降解完毕。

       

      Abstract: In order to reduce the dust disaster in the coal mine industry and reduce the probability of coal miners suffering from pneumoconiosis, the graft copolymerization method was adopted, and polyvinyl alcohol was used as the dust suppressant matrix material, under the action of an initiator and a cross-linking agent, 2-acrylamide-2-methylpropanesulfonic acid and acrylic acid are graft-copolymerized with a matrix to prepare a superabsorbent resin as a microcapsule core material. Using chitosan as the wall material, a new type of water-absorbing resin dust-suppressing microcapsules was prepared through the amine-aldehyde condensation of chitosan and glutaraldehyde. The encapsulation of water-absorbent resin and its microcapsules was determined by infrared spectrum analysis and scanning electron microscope. The swelling, moisture retention, wind erosion resistance, and biodegradability of the water-absorbent resin and its microcapsules were studied. The results showed that the microcapsules could swell up to 23 times, and the mass loss after 12 h was only 19.6 %. In the wind erosion resistance experiment, under the wind speed of 13 m/s, the dust suppression efficiency of the microcapsule dust suppressant is as high as 91.98 %, which inhibits the diffusion of coal dust. And after 22 days in the natural environment, the microcapsule dust suppressant can be degraded completely.

       

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